author
Bobby Brown
Post 2026-06-25
Polycarbonate (PC) Chemical Resistance & Properties

Contents


What is Polycarbonate (PC)?

Polycarbonate (PC) is a colorless, transparent, amorphous thermoplastic material. Due to its colorless transparency and excellent impact resistance, it is commonly used in various applications in our life such as the clear visor on a motorcycle helmet, the lens in your eyeglasses, reusable water bottles, baby bottles, CD and DVD discs, car headlight covers, clear smartphone cases, and the hard shell of a carry-on suitcase. In industrial settings, PC shows up as a wetted material in flow meters, sight glasses, and level indicators. Even the visor on NASA astronauts' helmets during moon landings was made from polycarbonate.


PC Material Properties

Mechanical Properties

Polycarbonate is a durable material with exceptionally high impact resistance — up to 250 times greater than standard glass.1 The characteristics of polycarbonate compare to those of polymethyl methacrylate (PMMA, acrylic), but polycarbonate is tougher and holds up better under extreme conditions. Although PC wins on toughness, PMMA has the edge on surface hardness — PC scratches relatively easily, which is why a hard protective coating is typically applied to PC eyewear lenses and automotive headlight covers. PC can also undergo large plastic deformations without cracking or breaking, meaning PC sheets can be cold-formed at room temperature using standard sheet metal bending techniques, even at tight angles, without needing heat. PMMA, by contrast, is brittle and will crack if bent cold.

Thermal Properties

Polycarbonate has a glass transition temperature of about 147 °C (297 °F), so it softens gradually above this point and flows above about 155 °C (311 °F).1 During manufacturing, tooling must be held above 80 °C (176 °F) to produce strain-free and stress-free products. There is also a grade trade-off worth knowing: lower molecular mass grades are easier to mold and process, but the resulting parts are weaker. The toughest PC parts come from higher molecular mass grades — they just require more care to process.

Under real operating conditions, the practical continuous-use limit is typically 115–130 °C — lower than the softening point alone suggests, because sustained mechanical load causes gradual dimensional change before the material visibly deforms. For high-temperature fluid handling applications, PVDF or PTFE-lined components are generally the more appropriate choice.

Optical Properties

Thermally processed polycarbonate is typically fully amorphous, resulting in high transparency to visible light — with better light transmission than many kinds of glass.1 PC also naturally blocks UV radiation without requiring additives, making it practical for applications needing UV protection without sacrificing transparency, such as polycarbonate roofing panels and outdoor protective covers.


Chemical resistance chart

Use this chart as a first-pass screening tool when evaluating PC for chemical-contact applications. Always follow up with physical testing under your actual operating conditions — temperature, concentration, and mechanical stress can all significantly affect real-world performance.

OK Recommended
Test before use
Not recommended
N/A No data
Ratings reflect single-chemical exposure. Where multiple chemicals are present simultaneously, material selection should be based on direct testing and engineering experience.
Category Chemical PC Rating
Organic acids Acetic acid OK (20%)
Acetic acid, glacial OK
Acetic anhydride
Citric acid OK
Organic compound Acetaldehyde
Acetone
Methyl alcohol OK (20%)
Aniline
Benzaldehyde
Benzene
Benzyl alcohol
Benzyl chloride N/A
Corn oil N/A
Ethanol OK
Ethylene glycol OK
Fatty acid OK
Formaldehyde OK (40%)
Formic acid OK
Hexane
Lactic acid OK
Methanol OK
Paraffin oil OK
Petroleum N/A
Phenol OK
Propane, liq
Propanol OK
Stearic acid OK
Tannic acid N/A
Tartaric acid OK
Toluene
Urea OK
Inorganic compound Ammonia
Ammonium chloride OK
Ammonium hydroxide
Ammonium nitrate N/A
Ammonium sulfate OK
Aqua regia
Barium chloride OK
Barium hydroxide
Brine N/A
Calcium chloride N/A
Calcium hydroxide
Carbonic acid OK
Chloric acid N/A
Chlorine N/A
Detergent
Hydrobromic acid N/A
Hydrochloric acid
Hydrofluoric acid
Hydrogen peroxide OK (30%)
Nitric acid OK (5%)   OK (40%)
Phosphoric acid OK (<40%)
Potassium hydroxide
Potassium nitrate OK
Potassium sulfate OK
Sodium carbonate OK
Sodium hydroxide
Sodium nitrate N/A
Sulfuric acid
Sulfur dioxide N/A

Frequently Asked Questions (FAQ)

Is polycarbonate chemically resistant?

PC has moderate chemical resistance. It performs well against dilute acids, alcohols, aliphatic hydrocarbons, and many aqueous salt solutions — but degrades quickly on contact with strong alkalis (sodium hydroxide, potassium hydroxide, ammonia), ketones (acetone), aromatic hydrocarbons (benzene, toluene), and concentrated strong acids. What makes some of these particularly dangerous is that damage can begin internally as stress cracking or swelling before it becomes visible on the surface. Always check the resistance chart for your specific chemical and concentration before specifying PC for any chemical-contact application.

What is polycarbonate's maximum working temperature?

PC's glass transition temperature is approximately 147 °C (297 °F), but in practice the continuous-use limit is typically 115–130 °C. The gap exists because sustained mechanical load causes gradual dimensional change — creep and stress relaxation — before any visible deformation occurs. When chemical exposure combines with elevated temperature, degradation accelerates further. For fluid handling applications that run hot, PVDF or PTFE-lined components are generally the safer choice.

How is polycarbonate different from acrylic (PMMA)?

PC and acrylic (PMMA) look nearly identical and are often used in similar applications, but they have a clear division of strengths. PC is significantly tougher — it resists impact far better (up to 250× glass vs. acrylic's ~17×) and can be cold-bent without cracking. Acrylic is more brittle but has better surface scratch resistance and offers slightly higher optical clarity (~92% light transmission vs. PC's ~88–90%). For chemical resistance, neither handles ketones or aromatic solvents well. The practical rule: choose PC where toughness and impact resistance take priority; choose acrylic where scratch resistance and optical perfection matter more and impact loads are low.

Is polycarbonate toxic?

Polycarbonate is not considered toxic under normal use conditions. The concern most commonly raised involves bisphenol A (BPA) — an industrial chemical used as a structural component in polycarbonate, present in food-contact PC applications since the 1960s.2 Small, measurable amounts of BPA can migrate from packaging into food — but based on the FDA's ongoing safety review of more than 300 scientific studies, BPA is safe at the levels occurring in foods from currently approved uses in food containers and packaging.2

It's worth noting that PC-based baby bottles and sippy cups were removed from FDA regulations — but this was because manufacturers had already abandoned those uses, not because of a safety finding.2 For industrial fluid handling, the more relevant question is chemical compatibility: whether the process fluid attacks the PC component, not whether PC itself is hazardous to handle.

Why is polycarbonate used in rotameters and sight glasses?

PC is a practical choice for rotameters, sight glasses, and level indicators where visual confirmation of flow or fluid level is needed. Its high optical clarity and impact resistance make it well suited for transparent fluid-contact components under moderate conditions. The key constraint is chemical compatibility: verify the process fluid against the resistance chart before specifying PC, and confirm operating temperatures stay within the continuous service limits. For aggressive chemicals or high-temperature streams, borosilicate glass or PVDF are more appropriate alternatives.

LORRIC's rotameter lineup includes PC tube options for clean water, cooling water, and low-aggression fluid monitoring applications. View LORRIC rotameters →

What chemicals should never contact polycarbonate?

Avoid exposing PC to: strong bases (sodium hydroxide, potassium hydroxide, ammonia, ammonium hydroxide, barium hydroxide, calcium hydroxide), ketone solvents (acetone), aromatic hydrocarbons (benzene, toluene), chlorinated solvents, and concentrated strong acids including hydrochloric acid, sulfuric acid, and hydrofluoric acid. These cause rapid degradation — stress cracking, swelling, or dissolution — often without obvious surface warning at early stages. All are marked in the resistance chart above.

Reference

  1. ^ Polycarbonate - wikipedia
  2. ^ Bisphenol A (BPA): Use in Food Contact Applications — U.S. Food & Drug Administration
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